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Adsorption of nickel (II) from aqueous solutions with clay-supported nano-scale zero-valent iron synthesized from green tea extract
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| dc.contributor.author | Tchakounte, Armand | |
| dc.contributor.author | Kede, Charles | |
| dc.contributor.author | Shikuku, Victor | |
| dc.contributor.author | Lenou, Idriss | |
| dc.contributor.author | Dika, Joseph | |
| dc.date.accessioned | 2024-11-20T06:53:24Z | |
| dc.date.available | 2024-11-20T06:53:24Z | |
| dc.date.issued | 2024 | |
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Table 3 Adsorption kinetic data for the removal of Ni2+ions by Arg and CnZVI. Adsorption kinetic model Arg CnZVI Qe,exp 8.361 14.250 Pseudo first-order Qe (mgg− 1) 10.066 13.131 K1 (min− 1) 0.178 0.255 R 2 0.988 0.951 Pseudo second-order Qe (mgg− 1) 10.752 13.950 K2 (gmg− 1min− 1) 0.027 0.032 R 2 0.986 0.984 Elovich kinetic model α (mgg− 1min− 1) 0.192 0.272 β(gmg− 1) 386.416 2280.524 R 2 0.962 0.996 Table 4 A comparison of Ni2+ adsorption capacity of Arg and CnZVI with other adsorbents. Adsorbents Qe (mg/g) Reference Rice husks 8.86 [51] Halzenut shell 10.10 [52] Fly ash 0.03 [53] Protonated rice bran 46.51 [54] Clinoptilolite 0.90 [55] Banana peel 6.80 [56] Row down seed 3.24 [57] Arg 10.85 This study CnZVI 14.38 This study Table 5 Result of Batch Test using CnZVI. Metals ions Ni2+ Cu2+ Zn2+ Hg2+ Pb2+ Cd2+ Qe (mg/g) 14.38 65.20 20.95 11.23 48.25 12.23 A. Tchakounte et al.Desalination and Water Treatment 320 (2024) 100771 11 [4] Sushil R, Manning B, Laurent C, Heechul C. 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| dc.identifier.uri | http://erepository.kafuco.ac.ke/123456789/248 | |
| dc.description.abstract | Nano zerovalent iron (nZVI) supported adsorbents have been reported as suitable candidates for adsorption of water contaminants. However, the role of and interplay between surface chemistry, functional group density and textural properties has largely been unexplored. In this work, green tea derived nano zerovalent iron (nZVI) supported clay hybrid material (CnZVI) was used as a novel adsorbent for the removal of Ni2+ ions from water. The unmodified natural clay (Arg) and the CnZVI composite were characterized using FTIR, SEM, TGA and BET techniques. Incorporation of nZVI ameliorated the specific surface area from 16.88 to 30.46 m2/g, translating to ~80 % increase. This translated to ~69 % increase in maximum adsorption capacity from 8.47 to 14.38 mg/g, respectively. The addition of nZVI in the clay decreased the affinity (KF) for Ni2+ by ~48 %. The disparity between the percent increase in surface area (~80 %) and the adsorption capacity (~69 %) implies the adsorption of Ni2+ was significantly controlled by textural properties compensating for the antagonistic effects of functional group density. The kinetic rates were best predicted by the pseudo-first-order and Elovich’s models for the Arg and CnZVI, respectively, implicit evidence of the role of surface chemistry. A maximum adsorption capacity of 14 mg/g was achieved for 100 mg Ni2+/L in 120 min for CnZVI. | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | Elsevier Inc | en_US |
| dc.subject | Green tea Incorporation Clay Kinetics study Surface chemistry | en_US |
| dc.title | Adsorption of nickel (II) from aqueous solutions with clay-supported nano-scale zero-valent iron synthesized from green tea extract | en_US |
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